Yes, absolutely. As a teacher or School Admin of the system, you can sign up a parent for the time slot they want.

Go to the class signup page and click the blue Sign Up button next to the conference time.

Select the student/parent name from a drop-down menu.

You can add a private note that is not visible to parents.

Click Save.
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To cancel an attendance, go to the time slot and click the pen icon next to the parent name. Select Cancel Attendance.